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16 Sep 2008 ... Demonstrates creating EAN - 13 Barcodes with VB. NET . .net ean 13 EAN13 Barcode Control - CodeProject
16 Sep 2008 ... Demonstrates creating EAN - 13 Barcodes with VB . NET .
route was signi cantly improved. The Wittig reaction of aldehyde 29 with ylide derived from compound 30, and followed by two steps of transformations, provided epoxide 32. The following epoxide-opening reaction of 32 by terminal alkyne 14 afforded the desired linear skeleton. The aldol-based protocol elaborated the lactone moiety on this intermediate, and annonacin was given after nal deprotections.31,33 Hanessian and Grillo tried to identify the stereochemistries of the THF region of annonacin A by the total synthesis. Unfortunately, they only obtained pseudoannonacin A, a diastereomeric isomer of annonacin A (Scheme 10-10).36 The key THF-containing segment 35 and sulfone 37 were prepared from L- and D-glutamic acid-derived chirons, respectively. Treatment of sulfone 37 with n-BuLi and then condensation with ester 35 afforded 38. Reductive removal of sulfone followed by reduction of ketone functionality and two-carbon extension at the right side gave skeleton intermediate 39. The lactone unit of target was introduced by the aldol strategy. Final deprotections gave a mixture of epimers at C-10, pseudoannonacin A. The relative con guration of the THF region of pseudoannonacin A is threo-trans-erythro (from left to right in Scheme 10-9). A series of chiral stannic synthons was developed and applied successfully into the synthesis of acetogenins by Marshall Jiang. In the synthesis of longifolicin vb.net ean 13 . NET EAN - 13 Generator - Create 1D EAN - 13 Barcode in . NET ...
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